Borides Superconduct at 32 K Under Pressure 2023
Few systems have Tc values above 30 K since mercury's superconductivity was found over a century ago.
ShanghaiTech University and Renmin University of China have observed superconductivity up to 32 K in MoB2 under pressure—the greatest Tc in transition-metal borides to date.
Their February 14, 2023 National Science Review article discusses high-Tc superconductors in transition metal borides.
Molybdenum diboride (MoB2) is unique in the MB2 family since it possesses both an AlB2-type and a CaSi2-type phase. Synchrotron X-Ray diffraction (XRD) shows that above 65 GPa, β-MoB2 transforms to α-MoB2, which has the same crystal structure as MgB2.
A question arises naturally: is it possible to achieve superconductivity in MoB2 under high pressure. So, we carried out the in-situ hi...